On the Stability of Co<sub>3</sub>O<sub>4</sub> Oxygen Evolution Electrocatalysts in Acid
Marco Etzi, Matthijs van Velzen, Jan P. Hofmann, Emiel J. M. Hensen
Abstract
Abstract Oxygen evolution reaction (OER) electrocatalysts suitable to work in acid are typically restricted to platinum group noble metal oxides because of their high activity and, especially, stability. Co 3 O 4 is currently explored as an alternative OER catalyst. Herein we prepared Co 3 O 4 films on fluorine‐doped Sn oxide (FTO) glass and Ti foil via thermal decomposition of nitrate salts and evaluated their activity and stability in 0.05 M H 2 SO 4 . Crystalline Co 3 O 4 films deposited on FTO were stable during chronopotentiometry at 10 mA cm −2 for over 16 hours. The dissolution rate was 61 ng Co cm −2 min −1 . The choice of a stable support such as FTO is essential to ensure the stability of the catalyst‐substrate interface and to prevent substrate passivation under OER conditions. Doping Co 3 O 4 with Li resulted in a higher OER activity under acidic conditions to be attributed to the larger electrochemical surface area, although the stability was impeded compared to undoped Co 3 O 4 .