Y<sub>2</sub>Mo<sub>4</sub>O<sub>15</sub>:Er<sup>3+</sup>/Tm<sup>3+</sup>/Yb<sup>3+</sup> Nanophosphors for High-Sensitivity Optical Temperature Sensing
Nozha Ben Amar, Kamel Saidi, Christian Hernández‐Álvarez, Mohamed Dammak, Inocencio R. Martín
Abstract
High Resolution Image Download MS PowerPoint Slide Noncontact optical nanothermometers are increasingly recognized for their high temperature resolution (δT), excellent relative thermal sensitivity (S r > 1% K –1 ), rapid response times (t < 0.1 s), and robust long-term optical stability. In this study, upconversion nanoparticles (UCNPs) based on Y 2 Mo 4 O 15 nanophosphors, codoped with 2% Er 3+, 1% Tm 3+, and x% Yb 3+ (x = 5, 10, 15 and 20%), were synthesized using the sol–gel method. The crystal structure, morphology, luminescence mechanisms, and temperature-sensing capabilities of these nanoparticles were systematically characterized. Under 975 nm laser excitation, the UCNPs exhibited intense upconversion luminescence, with emission peaks corresponding to well-defined energy-level transitions of Er 3+ and Tm 3+ ions. Temperature-dependent luminescence spectra were measured over the 300–520 K range using the fluorescence intensity ratio technique. The material exhibits both thermally coupled levels (TCLs) and nonthermally coupled levels, resulting from intraionic and interionic transitions involving Er 3+ –Er 3+, Tm 3+ –Tm 3+, Er 3+ –Tm 3+, and Tm 3+ –Er 3+ interactions. This complex energy-transfer network significantly enhances the temperature-sensing performance. Among the investigated transitions, the intensity ratio I 700 /I 806 derived from the TCL approach showed the highest relative sensitivity, reaching S r = 2.18% K –1 at 300 K. Additionally, the system achieved a minimum temperature uncertainty of δT = 0.26 K. These findings highlight the superior thermometric performance of the synthesized nanophosphors and underscore their potential for optimization through the synergistic interplay of multiple luminescent centers. This work validates the applicability of these nanomaterials for advanced optical nanothermometry and provides a foundation for developing next-generation temperature nanosensors.