Engineering Shapes and Sizes of Molecular Crystals to Achieve Versatile Photomechanical Behaviors
Fei Tong, Da‐Hui Qu
Abstract
Photomechanical molecular crystals, which can directly convert light energy to mechanical energy and do mechanical work at different scales, are promising for future photoactuators. However, one of the bottlenecks in this area is how to harness the crystal shapes and sizes to achieve desired photomechanical motions and behaviors for versatile functionalities. To date, numerous techniques and strategies have been explored and developed to overcome this obstacle. In this perspective, we will summarize the progress recently made on the crystal shape and size engineering platform. Then we briefly touch on possible applications of photomechanical molecular crystals by introducing some built photoresponsive implementations. Finally, we will identify some fundamental challenges and suggestions for future applications.