Electrochemical proton-coupled electron transfer of an anthracene-based azo dye
Amanda N. Oldacre, Elizabeth R. Young
Abstract
Herein, we report the thermodynamics, kinetics, and mechanism for electrochemical proton-coupled electron transfer involving the anthracene-based azo dye azo-OMe.
Topics & Concepts
ChemistryAnthraceneElectron transferElectrochemistryCyclic voltammetryAcetonitrileTafel equationKinetic isotope effectProtonProton-coupled electron transferTrifluoroacetic acidPhotochemistryReaction rate constantVoltammetryKineticsInorganic chemistryPhysical chemistryElectrodeOrganic chemistryDeuteriumPhysicsQuantum mechanicsPhotochromic and Fluorescence ChemistryFree Radicals and AntioxidantsPhotochemistry and Electron Transfer Studies