Selection of Manganese oxide catalysts for catalytic oxidation of Carbon monoxide at ambient conditions
Subhashish Dey, Niraj Singh Mehta
Abstract
Carbon monoxide (CO) is one of the very poisonous gases present in the atmosphere and low temperature complete oxidation CO is very important process for all human being present in the environment. A catalytic converter was an emission control device that converts more toxic gases present in the automobile exhaust into less toxic gases by the catalytic reactions. The manganese oxide catalysts i.e. (XMn2Ox, X = Ce, Co, Fe, Cu) are prepared into laboratory by the co-precipitation method followed by calcinations in reactive CO–air mixture and traditional calcinations conditions. The activity order of catalysts for CO oxidation is as follows: CuMn2O2 > CeMn2O2 > CoMn2O2 > FeMn2O2. Among all the prepared catalysts, the CuMn2O2 has showed that the best catalytic activity for CO oxidation at the low temperature. The complete oxidation of CO was achieved at 85 ºC over CuMn2RC catalyst. The calcinations strategies of precursors have great influenced on the activity of resulting catalysts. The CO oxidation activity was recognized to be a combination of factors including high surface area, active surface oxygen species and Mn(IV) cations. These results provide a novel thought to design the highly active CuMn2O2 catalyst.