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Understanding, quantifying, and controlling the molecular ordering of semiconducting polymers: from novices to experts and amorphous to perfect crystals

Zhengxing Peng, Long Ye, Harald Ade

2021Materials Horizons249 citationsDOIOpen Access PDF

Abstract

) and thermal transitions. A small database is presented for 13 representative conjugated and insulating polymers ranging from amorphous to semi-paracrystalline. Finally, we outline the challenges to rationally design more perfect polymer crystals and propose a new molecular design approach that envisions conceptual molecular grafting that is akin to strained and unstrained hetero-epitaxy in classic (compound) semiconductors thin film growth.

Topics & Concepts

Amorphous solidMaterials sciencePolymerNanotechnologyChemical physicsCrystallographyChemistryComposite materialConducting polymers and applicationsOrganic Electronics and PhotovoltaicsAdvanced Memory and Neural Computing