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Contact resistivity due to oxide layers between two REBCO tapes

Jun Lu, Yan Xin, Eric Lochner, Kyle Radcliff, Jeremy Levitan

2020Superconductor Science and Technology25 citationsDOIOpen Access PDF

Abstract

Abstract In a no-insulation (NI) REBCO magnet, the turn-to-turn contact resistivity ( ρ c ) determines its quench self-protection capability, charging delay time and the energy loss during field ramps. Therefore it is critically important to be able to control a range of ρ c values suitable for various NI magnet coils. In this work, we investigate two possibilities to control ρ c : by controlling the oxide layer of the copper surface of REBCO tapes; and by controlling the oxide layer in stainless steel co-wind tapes. We used a commercial oxidizing agent Ebonol ® C to treat the copper surface of REBCO tapes. The copper oxide layer was characterized by cross-sectional transmission electron microscopy (TEM) and x-ray photoelectron spectroscopy (XPS). The oxide layer formed in Ebonol ® C at 98 °C for 1 min is Cu 2 O of 0.5–1 μ m. The ρ c between two oxidized REBCO is in the order of 35 mΩ cm 2 at 4.2 K which decreases to 10 mΩ cm 2 after 30 000 contact pressure cycles. The ρ c increases but only by 5% at 77 K. We also investigated the effect of oxidation of stainless steel co-wind tape on ρ c . The native oxides on 316 stainless steel tape as well as those heated in air at 200 °C–600 °C were examined by TEM and XPS. The native oxides layer is about 3 nm thick. After heating at 300 °C for 8 min and 600 °C for 1 min, its thickness increases to about 10 and 30 nm respectively. For the stainless steel tapes with about 10 nm surface oxides, pressure cycling for 30 000 cycles decreases ρ c by almost 4 orders of magnitude. Whereas at 77 K, it only decreases by a factor of 3. For a surface with 30 nm oxide, the ρ c decreases moderately with load cycles. The results suggest that for an oxidized stainless steel to achieve stable ρ c over large number of load cycles a relatively thick oxide film is needed.

Topics & Concepts

Materials scienceOxideOxidizing agentLayer (electronics)CopperX-ray photoelectron spectroscopyCopper oxideElectrical resistivity and conductivityComposite materialTransmission electron microscopyMetallurgyChemical engineeringScanning electron microscopeContact areaSurface layerAtmospheric temperature rangeElectrical conductorElectrical contactsEnergy-dispersive X-ray spectroscopyContact resistanceAtmospheric pressurePhysics of Superconductivity and MagnetismSuperconductivity in MgB2 and AlloysSuperconducting Materials and Applications
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