Principles of melting in hybrid organic–inorganic perovskite and polymorphic ABX <sub>3</sub> structures
Bikash Kumar Shaw, Celia Castillo‐Blas, Michael F. Thorne, María Laura Ríos Gómez, Tom Forrest, Maria Diaz‐Lopez, Philip A. Chater, Lauren McHugh, David A. Keen, Thomas D. Bennett
Abstract
with metal replacement are observed with each A-site cation, with Co < Fe < Mn. The majority of the melts formed were found to recrystallise partially upon cooling, though glasses could be formed through a small degree of organic linker decomposition. Total scattering methods are used to provide a greater understanding of the melting mechanism.
Topics & Concepts
ABX testPerovskite (structure)Materials scienceCrystallographyChemistryChemical physicsMathematicsStatisticsPerovskite Materials and ApplicationsSolid-state spectroscopy and crystallographyThermal Expansion and Ionic Conductivity