Photoinduced C(sp<sup>3</sup>)–H sulfination empowers the direct and chemoselective introduction of the sulfonyl group
Shengfei Jin, Graham C. Haug, Ramon Trevino, Viet D. Nguyen, Hadi D. Arman, Oleg V. Larionov
Abstract
The photoinduced C–H sulfination of abundant aliphatic C–H bonds provides direct access to all major classes of organosulfur compounds via the intermediacy of synthetically versatile sulfinate salts.
Topics & Concepts
SulfonylGroup (periodic table)ChemistryMedicinal chemistryStereochemistryOrganic chemistryAlkylSulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsCatalytic C–H Functionalization Methods