Silica-Based Superhydrophobic and Superoleophilic Cotton Fabric with Enhanced Self-Cleaning Properties for Oil–Water Separation and Methylene Blue Degradation
Waqas Ahmad, Naseer Ahmad, Sufian Rasheed, Muhammad Nabeel, Abrar Mohyuddin, Muhammad Tariq Riaz, Dilshad Hussain
Abstract
Superhydrophobic textiles with multifunctional characteristics are highly desired and have attracted tremendous research attention. This research employs a simple dip-coating method to obtain a fluorine-free silica-based superhydrophobic and superoleophilic cotton fabric. Pristine cotton fabric is coated with SiO 2 nanoparticles and octadecylamine. SiO 2 nanoparticles are anchored on the cotton fabric to increase surface roughness, and octadecyl amine lowers the surface energy, turning the hydrophilic cotton fabric into superhydrophobic. The designed cotton fabric exhibits a water contact angle of 159° and a sliding angle of 7°. The prepared cotton fabric is characterized by attenuated total reflectance-fourier transform infrared spectroscopy, X-ray diffraction, atomic force microscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. In addition, the coated fabric reveals excellent features, including mechanical and chemical stability, superhydrophobicity, superoleophilicity, and the self-cleaning ability. SiO 2 nanoparticles and octadecylamine-coated cotton fabric demonstrate exceptional oil–water separation and wastewater remediation performance by degrading the methylene blue solution up to 89% under visible light. The oil–water separation ability is tested against five different oils with more than 90% separation efficiency. This strategy has the advantages of low-cost precursors, a simple and scalable coating method, enhanced superhydrophobicity and superoleophilicity, self-cleaning ability, efficient oil–water separation, and exceptional wastewater remediation performance.