Ultramicroporous hydrogen-bond decorated robust metal–organic framework for high xenon capture performances
Min‐Jung Kang, Jong Hyeak Choe, Hyojin Kim, Hongryeol Yun, Dae Won Kim, Chang Seop Hong
Abstract
A ultramicroporous metal–organic framework Ni(AIN)2 exhibited ideal performance of both high Xe/Kr selectivity and high Xe adsorption at low pressures. The amino groups of the AIN ligands form intra- and inter-net hydrogen bonds, imparting structural stability even under wet conditions.
Topics & Concepts
XenonHydrogen bondAdsorptionMetal-organic frameworkHydrogenSelectivityMetalMaterials scienceChemistryChemical engineeringInorganic chemistryOrganic chemistryMoleculeCatalysisEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsMagnetism in coordination complexes