Mixed-halide triphenyl methyl radicals for site-selective functionalization and polymerization
Lisa Chen, Mona E. Arnold, Rémi Blinder, Fedor Jelezko, Alexander J. C. Kuehne
Abstract
-bromide. The mixed halide radicals give access to complex, and so far inaccessible luminescent open-shell small molecules, as well as polymers carrying the radical centers in their backbone. The new mixed-halide triphenyl methyl radicals represent a powerful building block for customized design and synthesis of stable luminescent radicals.
Topics & Concepts
HalideRadicalSurface modificationChemistryPhotochemistryPolymerizationPolymer chemistryOrganic chemistryPolymerPhysical chemistryOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent MaterialsOrganometallic Complex Synthesis and Catalysis