Non‐Carbonized Pd Single‐Atom Catalyst Supported on Lignin‐Functionalized Phenolic Resin for Potent Catalytic Transfer Hydrogenation of Lignin‐Derived Aldehydes
Tairan Pang, Zhenglong Xue, Guanhua Wang, Junkai Li, Wenjie Sui, Chuanling Si
Abstract
Abstract Single‐atom catalysts (SACs) depend significantly on their support properties, and organic polymers have emerged as promising candidates due to their tunable physicochemical properties and diverse functional groups. However, the high‐temperature carbonization commonly required for conventional organic polymer‐supported SAC fabrication often leads to the loss of these functional groups, thus weakening metal‐support interactions and catalytic performance accordingly. Herein, we report a sustainable strategy to synthesize nitrogen‐functionalized lignin‐based phenolic resin (N‐LPR) supports for stabilizing atomically dispersed palladium (Pd) without carbonization. Using ammonia solution (NH 3 ·H 2 O) as both the nitrogen source and catalyst, high molecular weight lignin fractions (L3) were transformed into N‐L3PR‐50% supports with a unique nano‐chain‐like structure, high surface area, and abundant amine groups, which can directly anchor Pd sites under room temperature. The resulting Pd@N‐L3PR‐50% catalyst achieved approximately 100% vanillin conversion and 97.91% selectivity for 2‐methoxy‐4‐methylphenol at 80 °C with excellent cycle stability and adaptability to lignin‐derived aldehydes, benefiting from the stable Pd‐N coordination and the good adsorption capacity provided by the N‐L3PR‐50% support. Consequently, this work not only demonstrates a straightforward non‐carbonation strategy to prepare lignin‐based SACs for potent biomass‐derived chemical transformations but also provides a novel avenue for the application of conventional multifunctional organic polymers as support for SACs.