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Preparation of N,P Co-doped Porous Carbon Derived from Daylily for Supercapacitor Applications

Tianxiang Jin, Jingwei Su, Qingyun Luo, Wei Zhu, Haizhen Lai, Dejuan Huang, Chunyan Wang

2022ACS Omega42 citationsDOIOpen Access PDF

Abstract

Biomass-derived activated carbon is a widely used electrode material for supercapacitors. One of the keys to preparing high-performance activated carbon is the selection of appropriate precursors. Daylily is a common edible herb and is widely planted in Asia. It is rich in nitrogen and phosphorus, so it can be used as a precursor of heteroatom-doped activated carbon. Herein, a daylily-derived porous carbon with a large specific surface area and high content of heteroatoms has been successfully prepared by a simple carbonization method. The as-prepared carbon materials showed a remarkable specific capacitance of 299.1 F/g at 0.5 A/g and excellent cycling stability of 99.6% after 4000 cycles at a current density of 1 A/g. Moreover, the assembled symmetric supercapacitor showed a high energy density of 21.6 Wh/kg at a power density of 598.2 W/kg in 6 M KOH electrolyte. These results demonstrate that the daylily-derived porous carbon is an excellent material for high-performance supercapacitors.

Topics & Concepts

SupercapacitorHeteroatomCarbonizationMaterials scienceCarbon fibersActivated carbonElectrolyteCapacitanceChemical engineeringSpecific surface areaPower densityElectrodeChemistryOrganic chemistryComposite materialScanning electron microscopeCatalysisAdsorptionPhysical chemistryPhysicsRing (chemistry)EngineeringQuantum mechanicsComposite numberPower (physics)Supercapacitor Materials and FabricationConducting polymers and applicationsElectrocatalysts for Energy Conversion
Preparation of N,P Co-doped Porous Carbon Derived from Daylily for Supercapacitor Applications | Litcius