Electrochemically driven, cobalt–carbon bond-mediated direct intramolecular cyclic and acyclic perfluoroalkylation of (hetero)arenes using X(CF<sub>2</sub>)<sub>4</sub>X
Luxia Cui, Toshikazu Ono, Md Jakir Hossain, Yoshio Hisaeda
Abstract
X) is presented. The consecutive formation of cobalt-carbon bonds and generation of fluoroalkyl radicals by homolysis are the key steps for the reaction to proceed.
Topics & Concepts
Intramolecular forceCobaltCarbon fibersChemistryMaterials scienceStereochemistryOrganic chemistryComposite materialComposite numberFluorine in Organic ChemistryCatalytic C–H Functionalization MethodsCarbon dioxide utilization in catalysis