Controllable tertiary amine-promoted photoactivation metal-free carbonylation of aryl sulfonium salts to aryl carboxylic acid derivatives
Jiajun Zhang, Le‐Cheng Wang, Yuanrui Wang, Xiao‐Feng Wu
Abstract
This paper describes a new method for the activation of aryl radicals via EDA complexes without metals and photosensitizers for carbonylation with various nucleophilic reagents under visible light.
Topics & Concepts
ArylCarbonylationSulfoniumChemistryMetalCarboxylic acidSalt (chemistry)Organic chemistryCatalysisCarbon monoxideAlkylSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsRadical Photochemical Reactions