Synthesis and crystal structure of the simultaneous binding of Ni(<scp>ii</scp>) cation and chloride by the protonated 2,4,6 tris-(2-pyridyl)-1,3,5 triazine ligand: theoretical investigations of anion⋯π, π⋯π and hydrogen bonding interactions
Pampi Pal, Kinsuk Das, Md Anowar Hossain, Rosa M. Gomila, Antonio Frontera, Subrata Mukhopadhyay
Abstract
A new octahedral Ni(<sc>ii</sc>) complex of a protonated 2,4,6-tris(2-pyridyl)-1,3,5-triazine ligand has been synthesized and X-ray analysis exhibited cooperative anion–π and H-bonding interactions.
Topics & Concepts
ChemistryProtonationTrisLigand (biochemistry)OctahedronChlorideCrystal structure1,3,5-TriazineTriazineCrystallographyIonStereochemistryPolymer chemistryOrganic chemistryReceptorBiochemistrySynthesis and Characterization of Heterocyclic CompoundsDNA and Nucleic Acid ChemistryChemical Reaction Mechanisms