Triply Interlocked [2]catenanes: Rational Synthesis, Reversible Conversion Studies and Unprecedented Application in Photothermal Responsive Elastomer
Li‐Long Dang, Jie Zheng, Juzhong Zhang, Tian Chen, Yin‐Hang Chai, Hong‐Ru Fu, Francisco Aznárez, Shuiren Liu, Dong‐Sheng Li, Lu‐Fang Ma
Abstract
Abstract Triply interlocked [2]catenane complexes featuring two identical, mechanically interlocked units are extraordinarily rare chemical compounds, whose properties and applications remain open to detailed studies. Herein, we introduce the rational design of a new ligand precursor, L1 , suitable for the synthesis of six triply interlocked [2]catenanes by coordination‐driven self‐assembly. The interlocked compounds can be reversibly converted into the corresponding simple triangular prism metallacage by addition of H 2 O or DMF solvents to their CH 3 OH solutions, thereby demonstrating the importance of π⋅⋅⋅π stacking and hydrogen bonding interactions in the formation of triply interlocked [2]catenanes. Moreover, extensive studies have been conducted to assess the remarkable photothermal conversion performance. Complex 6 a , exhibiting outstanding photothermal conversion performance (conversion efficiency in solution : 31.82 %), is used to prepare novel photoresponsive elastomer in combination with thermally activated liquid crystal elastomer. The resultant material displays robust response to near‐infrared (NIR) laser and the capability of completely reforming the shape and reversible actuation, paving the way for the application of half‐sandwich organometallic units in photo‐responsive smart materials.