Understanding the Effect of the Electron Spin Relaxation on the Relaxivities of Mn(II) Complexes with Triazacyclononane Derivatives
Rocío Uzal-Varela, Laura Valencia, Daniela Lalli, Marcelino Maneiro, David Esteban‐Gómez, Carlos Platas‐Iglesias, Mauro Botta, Aurora Rodríguez‐Rodríguez
Abstract
, leads to a small ZFS energy, whereas this value increases as the coordination polyhedron approaches to a trigonal prism.
Topics & Concepts
ChemistryCrystallographyAmideRelaxation (psychology)Ligand (biochemistry)Electron paramagnetic resonanceMoleculeIonMetalComputational chemistryNuclear magnetic resonanceOrganic chemistryPsychologyPhysicsSocial psychologyBiochemistryReceptorMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies