<i>In situ</i> FTIR spectroscopic investigations on rhodium carbonyl complexes in the absence of phosphorus ligands under hydroformylation conditions
Benedict N. Leidecker, Dilver Peña Fuentes, Chunhong Wei, Mathias Sawall, Klaus Neymeyr, Robert Franke, Armin Börner, Christoph Kubis
Abstract
The composition of mixtures of rhodium carbonyl complexes in the absence of P-ligands under varying conditions relevant for hydroformylation have been studied by in situ FTIR spectroscopy.
Topics & Concepts
ChemistryHydroformylationRhodiumIn situFourier transform infrared spectroscopyPhosphorusCatalysisInorganic chemistryPolymer chemistryOrganic chemistryChemical engineeringEngineeringOrganometallic Complex Synthesis and CatalysisAsymmetric Hydrogenation and CatalysisCatalysis and Hydrodesulfurization Studies