Probing the electronic boundaries between trigonal and tetrahedral coordination at beryllium
Magnus R. Buchner, Matthias Müller, Nils Spang
Abstract
were synthesized and characterised via NMR and IR spectroscopy as well as X-ray diffractometry. Depending on the halide and the state of matter these are either mono- or dinuclear. Population analyses were performed to determine the influence of the metal's partial charge on the coordination geometry. Additionally, the reactivity of these compounds towards C-Cl- and O-H-bonds was studied.
Topics & Concepts
Reactivity (psychology)HalideBerylliumCrystallographyChemistryAdductCoordination complexTrigonal crystal systemMetalPopulationInorganic chemistryCrystal structureOrganic chemistryMedicineDemographyPathologySociologyAlternative medicineInorganic Fluorides and Related CompoundsSynthesis and characterization of novel inorganic/organometallic compoundsInorganic Chemistry and Materials