Lattice Structure and Pure Green Upconversion Luminescence of a BiTa <sub>7</sub> O <sub>19</sub> :Er <sup>3+</sup> /Yb <sup>3+</sup> Single Crystal
Xu Liu, Yongze Cao, Wangzhong Mu, Tian Chen, Hailong Zhang, Guangming Niu, Mengxue Cao, Changhao Yu, Yichao Wang, Jinsu Zhang, Xizhen Zhang, X. F. Li, B J Chen
Abstract
Using K 2 Mo 3 O 10 and B 2 O 3 as the solvent and BiTa 7 O 19:Er 3+ /Yb 3+ powder as the precursor, BiTa 7 O 19:Er 3+ /Yb 3+ single crystals were synthesized by the molten salt method in a platinum crucible. Utilizing scanning transmission electron microscopy (STEM) images recorded with a high-angle annular dark field (HAADF) detector and an annular bright field (ABF) detector, it is demonstrated that Er 3+ /Yb 3+ can replace the sites in the (Ta/Bi)O 6 layer and can also exist in the interstices between the (Ta/Bi)O 6 layer and the TaO 7 layer. BiTa 7 O 19:Er 3+ /Yb 3+ in the (Ta/Bi)O 6 layer has a disordered structure and belongs to the P 6 3 / mcm (193) space group, rather than the ordered P 6̅ c 2 (188) space group. Since three-layer TaO 7 stacking was observed, the growth mode of the single crystal was inferred to be a piece-by-piece stacking process of the precursor blocks. This is because using raw materials rather than precursors is not sufficient to grow large-sized single crystals with high-quality. Under 980 nm laser excitation, the sample emits pure green upconversion luminescence, which is caused by the 2D distribution of Er 3+ /Yb 3+ . The shift rate of the peak centroids reached 0.173 nm GPa –1 under high pressure. The absolute and relative temperature sensitivities reached 0.851% and 0.83% K –1, respectively. In phosphor-converted 980 nm LEDs fabricated based on the samples, the CIE color coordinate can reach (0.21, 0.75), which exceeds the NTSC standard. This indicates that this crystal can be used for pressure and temperature sensing, along with UCL display applications.