Selective cyclohexene oxidation with O<sub>2</sub>, H<sub>2</sub>O<sub>2</sub> and <i>tert</i>-butyl hydroperoxide over spray-flame synthesized LaCo<sub>1−x</sub>Fe<sub>x</sub>O<sub>3</sub> nanoparticles
Julia Büker, Barış Alkan, Qi Fu, Wei Xia, Jonas Schulwitz, Daniel Waffel, Tobias Falk, Christof Schulz, Hartmut Wiggers, Martin Muhler, Baoxiang Peng
Abstract
A series of spray-flame made LaCo<sub>1−x</sub>Fe<sub>x</sub>O<sub>3</sub> nanoparticles showed promising activity for liquid-phase cyclohexene oxidation. Various oxidizing agents, <italic>i.e.</italic>, O<sub>2</sub>, H<sub>2</sub>O<sub>2</sub> and <italic>tert</italic>-butyl hydroperoxide, led to different product selectivities.
Topics & Concepts
Oxidizing agentCyclohexeneCatalysisChemistryMaterials scienceOrganic chemistryCatalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsElectrocatalysts for Energy Conversion