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Photoluminescent coordination polymer bulk glasses and laser-induced crystallization

Zeyu Fan, Chinmoy Das, Aude Demessence, Ruilin Zheng, Setsuhisa Tanabe, Yong‐Sheng Wei, Satoshi Horike

2022Chemical Science21 citationsDOIOpen Access PDF

Abstract

) in the structures. The glasses are moldable and thermally stable, and over centimeter-sized glass monoliths were fabricated by the hot-press technique. They showed high transparency over 80% from the visible to near-infrared region and strong green emission at room temperature. Furthermore, the glass-to-crystal transformation was demonstrated by laser irradiation through the photothermal effect of the glasses.

Topics & Concepts

PhotoluminescenceLaserCrystallizationMaterials sciencePolymerChemical engineeringNanotechnologyOptoelectronicsOpticsComposite materialPhysicsEngineeringPhase-change materials and chalcogenidesGlass properties and applicationsCultural Heritage Materials Analysis