<i>trans</i>-Hydroboration–oxidation products in Δ<sup>5</sup>-steroids <i>via</i> a hydroboration-<i>retro</i>-hydroboration mechanism
J. Ciciolil Hilario-Martínez, Fernando Murillo, Jair García-Méndez, Eugenia Dzib, Jesús Sandoval-Ramı́rez, Miguel‐Ángel Muñoz‐Hernández, Sylvain Bernès, László Kürti, Fernanda Duarte, Gabriel Merino, María A. Fernández‐Herrera
Abstract
-structure and the subsequent hydroboration by the β-face. Besides, the corresponding Markovnikov type products have been isolated in synthetically useful yields. The behavior of the reaction under a range of temperatures is also investigated.
Topics & Concepts
HydroborationChemistryStereochemistryOrganic chemistryCatalysisChemical Synthesis and ReactionsAsymmetric Synthesis and CatalysisChemical Synthesis and Analysis