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Popcorn‐Derived Porous Carbon Based Electrochemical Sensor for Simultaneous Determination of Hydroquinone, Catechol and Nitrite

Zhenyong Lu, Yue Wang, Yaming Zhu, Yasushi Hasebe, Zhiqiang Zhang

2022ChemistrySelect14 citationsDOI

Abstract

Abstract In this study, popcorn‐derived microporous carbon (PPC) was prepared by pyrolysis method under KOH activation, which was used as an electrochemical sensor material for simultaneous detection of hydroquinone (HQ), catechol (CC), and nitrite (NT). The prepared PPC/GCE exhibited highly electrocatalytic activity to the oxidation of HQ, CC and nitrite. The oxidation peaks for HQ (111 mV), CC (216 mV), and NT (854 mV) were well separated under the optimized conditions. The PPC/GCE showed a wide linear range of 3.0–700 μM, 3.0–500 μM and 5.0–10000 μM for HQ, CC and NT with detection limits of 1.45 μM, 0.49 μM and 1.5 μM, respectively. The KOH‐activated PPC is a promising electrode material for fabricating selective and sensitive electrochemical sensors.

Topics & Concepts

HydroquinoneMicroporous materialCatecholNitriteElectrochemistryElectrochemical gas sensorChemistryDetection limitInorganic chemistryNuclear chemistryElectrodeChromatographyOrganic chemistryNitratePhysical chemistryElectrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications
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