How Charges Separate when Surfaces Are Dewetted
Aaron D. Ratschow, Lisa S. Bauer, Pravash Bista, Stefan A. L. Weber, Hans‐Jürgen Butt, Steffen Hardt
Abstract
Charge separation behind moving water drops occurs in nature and technology. Yet, the physical mechanism has remained obscure, as charge deposition is energetically unfavorable. Here, we analyze how a part of the electric double layer charge remains on the dewetted surface. At the contact line, the chemical equilibrium of bound surface charge and diffuse charge in the liquid is influenced by the contact angle and fluid flow. We summarize the mechanism in an analytical model that compares well with experiments and simulations. It correctly predicts that charge separation increases with increasing contact angle and decreases with increasing velocity.