A divergent construction of fused and bridged carbo-/heterocyclic scaffolds<i>via</i>cascade reactions of aryl azomethine imines with vinyl cyclic carbonates
Xinyuan Cai, Xia Song, Xueying Yang, Xinying Zhang, Xuesen Fan
Abstract
Presented herein is a divergent synthesis of indene-fused pyrazoles and bridged benzodiazepines tethered with a hydroxymethyl group through the cascade reactions of aryl azomethine imines with vinyl cyclic carbonates.
Topics & Concepts
ChemistryArylHydroxymethylIndeneCascadeCombinatorial chemistryPolymer chemistryOrganic chemistryChromatographyAlkylCatalytic C–H Functionalization MethodsCyclopropane Reaction MechanismsSynthesis and Catalytic Reactions