An unprecedented Cu<sub>6</sub> cluster-based bimetallic MOF with multiple open sites for high CO<sub>2</sub> capture and efficient CO<sub>2</sub> conversion
Xueyue Yu, Jiaming Gu, Baobing Tang, Tong Xu, Guanghua Li, Zhiyong Chang, Yunling Liu
Abstract
Through soft-hard acid-base theory, a novel bimetallic MOF ( JLU-MOF108 ) with an unprecedented 12-connected Cu 6 cluster SBU was synthesized. LAS and LBS inside JLU-MOF108 exhibited significant CO 2 capture and conversion capability.
Topics & Concepts
Bimetallic stripCluster (spacecraft)ChemistryMaterials scienceCatalysisComputer scienceOperating systemOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials ScienceInorganic Fluorides and Related Compounds