Mechanism of recalcification and its effects on the microstructure and transport properties of cement paste
Thinh Nguyen, Quoc Tri Phung, N. Maes, Lander Frederickx, Rodrigo de Oliveira Silva, Dimitrios Sakellariou, Geert De Schutter, Özlem Çizer
Abstract
Calcium leaching involves the removal of calcium ions from the pore solution and hydration products, leading to a decrease in pH, coarsening of pore structure, and, in severe cases, loss of cohesion, shrinkage, and cracking. Recalcification is a restoration process aiming at repairing degraded C-S-H structures by externally supplying calcium ions. However, our understanding of recalcification mechanism, its potential to reverse calcium leaching, and its effects on deteriorated cementitious matrices remains limited. This study aims at enhancing the understanding of the impact of recalcification on calcium leached cement pastes. Our findings demonstrate that calcium leaching can be partially reversed by immersion in a saturated calcium hydroxide solution. Recalcification functions by introducing calcium ions to the degraded matrix, triggering a reaction with the degraded C-S-H. This process reverses silicate polymerization, increases the Ca/Si ratio in the degraded zone’s, and densifies the pore structure. After only 14 days of recalcification, the degraded portion experienced a 50 % reduction in porosity, an increase in pH. By day 28, recalcification halved the permeability of the treated sample and completely consumed all silica gel. Additionally, our findings reveal that higher temperatures adversely affect the structure of C-S-H, hindering the beneficial structural modifications facilitated by recalcification.