Iridium-catalyzed selective amination of B(4)–H for the synthesis of<i>o</i>-carborane-fused indolines
Caiyan Zhang, Ke Cao, Dechun Liu, Han‐Bo Yang, Chao-Chao Teng, Bo Li, Junxiao Yang
Abstract
An iridium-catalyzed selective amination of B(4)–H via dehydrogenative cross-coupling of B–H/N–H bonds for the synthesis of o -carborane-fused indolines has been developed for the first time.
Topics & Concepts
AminationCarboraneIridiumChemistryCombinatorial chemistryCatalysisReductive aminationOrganic chemistryBoron Compounds in ChemistryOrthopedic Infections and TreatmentsRadiopharmaceutical Chemistry and Applications