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Mechanochemical synthesis of π-conjugated naphthotetrathiophene-based covalent organic frameworks and their post-modification <i>via</i> the Doebner reaction

Mohammad Hossein Gohari, Pegah Ghamari, Ehsan Hamzehpoor, Farshid Effaty, Tomislav Friščić, Dmitrii F. Perepichka

2025Chemical Science5 citationsDOIOpen Access PDF

Abstract

Mechanochemical synthesis of isomeric π-conjugated COFs (2TTN and 3TTN) with tunable optical and electronic properties, enhanced stability via quinoline linkages, and notable proton conductivity.

Topics & Concepts

Conjugated systemCovalent bondChemistryOrganic synthesisCombinatorial chemistryOrganic chemistryChemical engineeringNanotechnologyMaterials scienceCatalysisEngineeringPolymerCovalent Organic Framework ApplicationsLuminescence and Fluorescent MaterialsPolydiacetylene-based materials and applications
Mechanochemical synthesis of π-conjugated naphthotetrathiophene-based covalent organic frameworks and their post-modification <i>via</i> the Doebner reaction | Litcius