<i>In situ</i> activation of COOH-functionalized ZIF-90-enabled reductive CO<sub>2</sub><i>N</i>-formylation
Kaixun Zhu, Li Y, Zhengyi Li, Yixuan Liu, Hongguo Wu, Hu Li
Abstract
A heterogeneous COOH-functionalized ZIF-90 porous catalyst (ZIF-90-C) was prepared for enhanced CO 2 adsorption/activation, and the in situ generated –COO − species can efficiently promote the N -formylation reaction.
Topics & Concepts
FormamidesFormylationChemistryCatalysisIn situCombinatorial chemistryAmine gas treatingReductive eliminationOrganic chemistryCarbon dioxide utilization in catalysisCovalent Organic Framework ApplicationsOrganoboron and organosilicon chemistry