An acyclic aluminyl anion
Ross A. Jackson, Aidan J. R. Matthews, Petra Vasko, Mary F. Mahon, Jamie Hicks, David J. Liptrot
Abstract
The potassium aluminyl, K 2 [Al{N(Dipp)SiMe 3 } 2 ] 2 has been synthesised. Reaction with [HC{(CH 3 )C(Dipp)N} 2 ]MgI(OEt 2 ) forms [HC{(CH 3 )C(Dipp)N} 2 ]MgAl{N(Dipp)SiMe 3 } 2 , a monomeric, acyclic, magnesium aluminyl complex.
Topics & Concepts
ChemistryElectrophileNucleophileIodideMagnesiumYield (engineering)Medicinal chemistryLigand (biochemistry)PotassiumIonStereochemistryInorganic chemistryOrganic chemistryCatalysisMaterials scienceReceptorBiochemistryMetallurgyCoordination Chemistry and OrganometallicsSynthesis and characterization of novel inorganic/organometallic compoundsOrganometallic Complex Synthesis and Catalysis