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A conductive and sodiophilic Ag coating layer regulating Na deposition behaviors for highly reversible sodium metal batteries

Xiaomin Chen, Xunzhu Zhou, Zhuo Yang, Zhiqiang Hao, Jian Chen, Wenxi Kuang, Xiaoyan Shi, Xingqiao Wu, Lin Li, Shulei Chou

2024Chemical Science25 citationsDOIOpen Access PDF

Abstract

ion and electric field distribution. This enables remarkably low overpotentials and uniform Na plating/stripping behavior with ultrahigh Coulombic efficiency of 99.9% during 500 cycles. As expected, the enhanced electrochemical performance of the anode-less battery and anode-free battery coupled with Prussian blue is achieved with the help of Ag coating. This work emphasizes the role of the conductive and sodiophilic coating layer in regulating the Na deposition behaviors for highly reversible sodium metal batteries.

Topics & Concepts

Faraday efficiencyHomogeneousElectrical conductorLayer (electronics)CoatingDeposition (geology)Materials scienceAtomic layer depositionMetalElectric fieldSodiumChemical engineeringIonNanotechnologyElectrochemistryInorganic chemistryElectrodeComposite materialChemistryMetallurgyOrganic chemistryPaleontologyQuantum mechanicsSedimentThermodynamicsPhysicsBiologyEngineeringPhysical chemistryAdvanced Battery Materials and TechnologiesAdvancements in Battery MaterialsAdvanced battery technologies research
A conductive and sodiophilic Ag coating layer regulating Na deposition behaviors for highly reversible sodium metal batteries | Litcius