Heterometallic multinuclear nodes directing MOF electronic behavior
Otega A. Ejegbavwo, Anna A. Berseneva, Corey R. Martin, Gabrielle A. Leith, Shubham Pandey, Amy J. Brandt, Kyoung Chul Park, Abhijai Mathur, Sharfa Farzandh, Vladislav V. Klepov, Brittany J. Heiser, M. V. S. Chandrashekhar, S. Karakalos, Mark D. Smith, Simon R. Phillpot, Sophya Garashchuk, Donna A. Chen, Natalia B. Shustova
Abstract
= 5-nitroisophthalate). Through probing framework electronic profiles, we demonstrate structure-property relationships, and also highlight the necessity for both comprehensive analysis of trends in metal properties, and novel avenues for preparation of heterometallic multinuclear isoreticular structures, which are critical components for on-demand tailoring of properties in heterometallic systems.
Topics & Concepts
Modularity (biology)Metal-organic frameworkNode (physics)PorosityMaterials scienceMetalNanotechnologyTopology (electrical circuits)ChemistryPhysicsEngineeringOrganic chemistryMetallurgyComposite materialElectrical engineeringAdsorptionGeneticsQuantum mechanicsBiologyMetal-Organic Frameworks: Synthesis and ApplicationsNanocluster Synthesis and ApplicationsMagnetism in coordination complexes