Recent advances in oxidative catalytic applications of polyoxovanadate-based inorganic–organic hybrids
Ji-Kun Li, Chuanping Wei, Yinfeng Han, Changwen Hu
Abstract
oxygen bridges directly or indirectly to give zero-, one-, two- or three-dimensional supramolecular structures. The oxidative conversion of organic compounds, including thiophene derivatives, thioethers, alkanes, alcohols, and alkenes, and oxidative detoxification of a sulfur mustard simulant or degradation of lignin, along with the oxidative photo/electrocatalytic transformation of organic compounds catalyzed by POVH materials, are discussed in detail. Furthermore, the challenges and prospects toward the development of POVH catalysts are explored briefly from our perspectives.
Topics & Concepts
CatalysisOxidative phosphorylationChemistryNanotechnologyMaterials scienceOrganic chemistryBiochemistryPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation ChemistryChemical Synthesis and Reactions