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Palladium-catalyzed domino Heck cyclization/ring opening of sulfolenes/desulfitative coupling: regio- and stereoselective synthesis of alkylated conjugated dienes

Xin‐Xing Wu, Hao Ye, Hong Dai, Bing Yang, Yang Wang, Shufeng Chen, Lanping Hu

2020Organic Chemistry Frontiers23 citationsDOI

Abstract

An efficient cascade dienylation provides a range of alkylated conjugated diene compounds with the <italic>Z</italic>-configuration by introducing the C<sub>4</sub> unit directly.

Topics & Concepts

ChemistryConjugated systemStereoselectivityDominoPalladiumAlkylationCatalysisHeck reactionRing (chemistry)CascadeOrganic chemistryStereochemistryPolymerChromatographyCatalytic C–H Functionalization MethodsSulfur-Based Synthesis TechniquesCatalytic Cross-Coupling Reactions
Palladium-catalyzed domino Heck cyclization/ring opening of sulfolenes/desulfitative coupling: regio- and stereoselective synthesis of alkylated conjugated dienes | Litcius