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Analysis of the growth and physicochemical properties of the newly developed stilbazolium derivative 4-<i>N</i>,<i>N</i>-dimethylamino-4-<i>N</i>-methyl stilbazolium 2-formyl benzene sulfonate (DSFS) single crystal: an effective material for nonlinear optical applications

Anand Sekar, M. Usha Rani, S. Kalainathan, Ravi Shanker Babu

2022RSC Advances21 citationsDOIOpen Access PDF

Abstract

Fourier transform infrared (FTIR) spectroscopy. Linear optical constants such as cut-off wavelength, bandgap, extinction coefficient, Urbach energy, electrical conductivity and optical conductivity of the titular crystal were found from ultraviolet-visible-near infra-red spectroscopy (UV-Vis-NIR). The emission wavelength of the title crystal lies in the red region (620 nm), which was confirmed from the photoluminescence spectroscopy (PL). The surface nature of the grown ionic crystal was examined through the etching and atomic force microscopy (AFM) technique. With a He-Ne laser as the source, Z scan analysis was carried out to study the third-order nonlinear properties of the DSFS crystal.

Topics & Concepts

Crystal (programming language)PhotoluminescenceSingle crystalSpectroscopyChemistryFourier transform infrared spectroscopyMaterials scienceAnalytical Chemistry (journal)CrystallographyOpticsOptoelectronicsOrganic chemistryComputer scienceProgramming languageQuantum mechanicsPhysicsNonlinear Optical Materials ResearchLiquid Crystal Research AdvancementsCrystal structures of chemical compounds
Analysis of the growth and physicochemical properties of the newly developed stilbazolium derivative 4-<i>N</i>,<i>N</i>-dimethylamino-4-<i>N</i>-methyl stilbazolium 2-formyl benzene sulfonate (DSFS) single crystal: an effective material for nonlinear optical applications | Litcius