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Accelerated Discovery of Single‐Atom Catalysts for Nitrogen Fixation via Machine Learning

Sheng Zhang, Shuaihua Lu, Peng Zhang, Jianxiong Tian, Li Shi, Chongyi Ling, Qionghua Zhou, Jinlan Wang

2021Energy & environment materials77 citationsDOIOpen Access PDF

Abstract

Developing high‐performance catalysts using traditional trial‐and‐error methods is generally time consuming and inefficient. Here, by combining machine learning techniques and first‐principle calculations, we are able to discover novel graphene‐supported single‐atom catalysts for nitrogen reduction reaction in a rapid way. Successfully, 45 promising catalysts with highly efficient catalytic performance are screened out from 1626 candidates. Furthermore, based on the optimal feature sets, new catalytic descriptors are constructed via symbolic regression, which can be directly used to predict single‐atom catalysts with good accuracy and good generalizability. This study not only provides dozens of promising catalysts and new descriptors for nitrogen reduction reaction but also offers a potential way for rapid screening of new electrocatalysts.

Topics & Concepts

CatalysisGeneralizability theoryNitrogen atomAtom (system on chip)GrapheneNitrogenComputer scienceFeature (linguistics)ChemistryMaterials scienceBiological systemCombinatorial chemistryArtificial intelligenceNanotechnologyMathematicsOrganic chemistryStatisticsParallel computingBiologyPhilosophyGroup (periodic table)LinguisticsAmmonia Synthesis and Nitrogen ReductionAdvanced Photocatalysis TechniquesElectrocatalysts for Energy Conversion
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