Toward rational design of TADF two-coordinate coinage metal complexes: understanding the relationship between natural transition orbital overlap and photophysical properties
T. Li, Jonas Schaab, Peter I. Djurovich, Mark E. Thompson
Abstract
A series of twelve two-coordinate coinage metal, Cu, Ag and Au, complexes with carbene-metal-amide structures were prepared and used to study the correlation of the overlap between the hole and electron NTOs with the electronic and photophysical properties of these TADF emitters.
Topics & Concepts
Materials scienceMetalTransition metalAmideCrystallographyChemical physicsChemistryOrganic chemistryCatalysisMetallurgyOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent MaterialsMolecular Junctions and Nanostructures