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On the Operational Conditions’ Effect on the Performance of an Anion Exchange Membrane Water Electrolyzer: Electrochemical Impedance Spectroscopy Study

I. V. Pushkareva, Maksim A. Solovyev, S. I. Butrim, M. V. Kozlova, D. A. Simkin, Artem S. Pushkarev

2023Membranes41 citationsDOIOpen Access PDF

Abstract

The performance of an anion exchange membrane water electrolyzer under various operational conditions (including voltage, KOH-supporting electrolyte concentration, and flow rate) is studied using conventional time-domain technics and electrochemical impedance spectroscopy (EIS). The water electrolyzer EIS footprint, depending on the variation in operational conditions, is studied and discussed, providing valuable data on the faradaic and non-faradaic processes in MEA, considering their contribution to the total polarization resistance. The distribution of the AEMWE cell voltage contributions is valuable to accessing the key directions in the system performance improvement.

Topics & Concepts

Dielectric spectroscopyElectrolysisElectrolytePolymer electrolyte membrane electrolysisMaterials scienceElectrochemistryPolarization (electrochemistry)Faraday efficiencyElectrodialysisMembraneChemical engineeringAnalytical Chemistry (journal)ChemistryElectrodeEngineeringChromatographyPhysical chemistryBiochemistryHybrid Renewable Energy SystemsFuel Cells and Related MaterialsAdvanced battery technologies research
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