Confinement of Au<sup>3+</sup>-rich clusters by using Silicalite-1 for selective solvent-free oxidation of toluene
He Huang, Wanyue Ye, Caicheng Song, Yingcen Liu, Xiaotong Zhang, Shan Yu, Yuzhen Ge, Shufen Zhang, Rongwen Lu
Abstract
Synergistic catalysis of Au<sup>0</sup> and Au<sup>3+</sup> dual active sites confined in Silicalite-1 for selective solvent-free oxidation of toluene to benzaldehyde with molecular oxygen.
Topics & Concepts
TolueneBenzaldehydeCatalysisSolventChemistryMolecular oxygenPhotochemistryOrganic chemistryCatalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsNanocluster Synthesis and Applications