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A Simple Monte Carlo Approach to Estimate the Uncertainties of SST and δ<sup>18</sup>O<sub>sw</sub> Inferred From Coral Proxies

Takaaki K. Watanabe, Miriam Pfeiffer

2022Geochemistry Geophysics Geosystems21 citationsDOIOpen Access PDF

Abstract

Abstract The skeletons of massive corals inhabiting tropical and subtropical oceans grow over centuries. The chemical and isotopic compositions of their skeletons reflect changes in the marine environment and provide an archive of sea surface temperature (SST) and salinity at a high temporal resolution spanning decades to centuries. Stable oxygen isotope ratios in coral skeletons (δ 18 O c ) are an excellent proxy for SST and the stable oxygen isotopic composition in seawater (δ 18 O sw ). Variations in δ 18 O sw serve as a hydrological proxy and are routinely estimated by subtracting the SST component from δ 18 O c . The SST component of δ 18 O c is inferred from coral Sr/Ca (SST proxy). Both Sr/Ca and δ 18 O c are converted to SST units based on Sr/Ca‐ and (δ 18 O c –δ 18 O sw )‐SST calibrations. However, the exact slope values of the Sr/Ca‐SST and (δ 18 O c –δ 18 O sw )‐SST calibrations are challenging to assess, which hampers the reliable estimation of SST, δ 18 O sw , and their uncertainties. Here, we present a simple Monte Carlo approach to estimate variations in SST and δ 18 O sw together with their confidence intervals. Our approach improves on previous error propagation methods by including intercolonial differences of calibration slopes in addition to analytical errors. In addition, Monte Carlo experiments using adjusted errors suggest that uncertainties in the calibration slopes have a minor influence on estimates of SST and δ 18 O sw .

Topics & Concepts

Sea surface temperatureMonte Carlo methodCalibrationSeawaterGeologyProxy (statistics)Isotopes of oxygenEnvironmental scienceOceanographyPhysicsStatisticsMathematicsQuantum mechanicsGeochemistryCoral and Marine Ecosystems StudiesOceanographic and Atmospheric Processes