Decatungstate-Catalyzed C(<i>sp</i><sup>3</sup>)–H Sulfinylation: Rapid Access to Diverse Organosulfur Functionality
Patrick Sarver, Noah B. Bissonnette, David W. C. MacMillan
Abstract
)-rich scaffolds, including natural products and approved pharmaceuticals, providing efficient access to complex sulfur-containing products. To demonstrate the broad potential of this methodology for the divergent synthesis of pharmaceutically relevant molecules, procedures for the diversification of the sulfinic acid products into a range of medicinally relevant functional groups have been developed.
Topics & Concepts
Organosulfur compoundsChemistryCatalysisOrganic chemistrySulfurSulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsCatalytic C–H Functionalization Methods