Advances in allylic and benzylic C–H bond functionalization enabled by metallaphotoredox catalysis
Huifeng Yue, Chen Zhu, Long Huang, Abhishek Dewanji, Magnus Rueping
Abstract
Merging two powerful methodologies, metallaphoto-catalyzed benzylic and allylic C(sp 3 )–H bond functionalizations provide a series of general and mild approaches for diversification of alkylbenzenes and alkenes.
Topics & Concepts
Allylic rearrangementAlkylbenzenesCatalysisChemistrySurface modificationCombinatorial chemistryMoleculeOrganic chemistryPhysical chemistryCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsOxidative Organic Chemistry Reactions