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Nanoscale Visualization of Electrochemical Activity at Indium Tin Oxide Electrodes

Oluwasegun J. Wahab, Minkyung Kang, Gabriel N. Meloni, Enrico Daviddi, Patrick R. Unwin

2022Analytical Chemistry46 citationsDOIOpen Access PDF

Abstract

is about 20 times larger than that measured at the macroscale. This is attributed to macroscale ET being largely limited by lateral conductivity of the ITO electrode under electrochemical operation, rather than ET kinetics at the ITO/electrolyte interface, as measured by SECCM. This study further demonstrates the considerable power of SECCM for direct nanoscale characterization of electrochemical processes at complex electrode surfaces.

Topics & Concepts

Indium tin oxideChemistryElectrodeCyclic voltammetryLinear sweep voltammetryElectrochemistryScanning electrochemical microscopyElectrolyteElectron transferCharge transfer coefficientAnalytical Chemistry (journal)NanotechnologyMaterials sciencePhysical chemistryChromatographyElectrochemical Analysis and ApplicationsConducting polymers and applicationsAnalytical Chemistry and Sensors