Construction of the Skeleton of Lucidumone
Shiqiang Ma, Zhen Li, Peng-Fei Yu, Hongliang Shi, Hesi Yang, Jiuzhou Yi, Zheng Zhang, Xiaoguang Duan, Xingang Xie, Xuegong She
Abstract
The skeleton of lucidumone was constructed through oxidative dearomatization/intramolecular Diels-Alder reaction, Cu-mediated remote C-H hydroxylation, allyl oxidation, acid-promoted dynamic kinetic resolution cyclization, and benzylic oxidation.
Topics & Concepts
ChemistrySkeleton (computer programming)StereochemistryComputer scienceProgramming languageBioactive Natural Diterpenoids ResearchChemical synthesis and alkaloidsPlant-based Medicinal Research