How Photocatalyst Dosage and Ultrasound Application Influence the Photocatalytic Degradation Rate of Phenol in Water: Elucidating the Mechanisms Behind
Wim Van de Moortel, Mohammadreza Kamali, Kristel Sniegowski, Leen Braeken, Jan Degrève, Jan Luyten, Raf Dewil
Abstract
Photocatalysis is of high interest for the treatment of wastewater containing non-biodegradable organic components. In this work, the photocatalytic degradation of phenol by TiO2 photocatalysis was assessed, the influence of ultrasound (US) treatment was evaluated, and the mechanisms behind it were elucidated. It was shown that the TiO2 concentration (in suspension) has a large influence on the degradation kinetics. At high TiO2 concentrations, a reduced efficiency was observed due to the shielding of the UV light by TiO2 particles. US treatment effectively increased phenol degradation by improving the mass transfer while it was shown by the experimental data that particle deagglomeration did not play a significant role. The degradation mainly occurred through indirect phenol oxidation by hydroxyl (OH*) radicals, which were formed in situ at the surface of the photocatalyst. Finally, based on the partial least squares (PLS) methodology, a mathematical model was developed, representing phenol degradation as a function of the selected process conditions.