Research Progress on New Catalytic Reaction Systems for Asymmetric Synthesis of Silicon-Stereogenic Center Containing Compounds
Yan Zeng, Fei Ye
Abstract
In the past two decades, organosilicon compounds bearing silicon-stereogenic centers have attracted extensive attention in the fields of organic synthesis, materials, and drug design.However, the expansion of organosilicon compounds in these fields has been greatly restricted by limited source of organosilicon compounds.Therefore, the development of highly efficient and selective asymmetric catalytic methods to obtain chiral organosilicon compounds with silicon-stereogenic centers is a challenging task that needs to be solved urgently.The latest research progress on new catalytic reaction systems for asymmetric synthesis of silicon-stereogenic center containing organosilanes since 2011 is mainly summarized.
Topics & Concepts
StereocenterChemistryCatalysisCenter (category theory)SiliconCombinatorial chemistryStereochemistryOrganic chemistryEnantioselective synthesisCrystallographyAsymmetric Synthesis and CatalysisCatalytic C–H Functionalization MethodsAsymmetric Hydrogenation and Catalysis